The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Alkenes,polyenes+radicals / Alkene radicals / CH2=CHCH2 / Jenkin(1993)_296K_210-232.5nm

DATAFILE: CH2=CHCH2_Jenkin(1993)_296K_210-232.5nm.txt
NAME: allyl radical
FORMULA: CH2=CHCH2
AUTHOR(YEAR): Jenkin(1993)
T: 296K
λ: 210-232.5nm
BIBLIOGRAPHY: M.E. Jenkin, T.P. Murrells, S.J. Shalliker, and G.D, Hayman, "Kinetics and product study of the self-reactions of allyl and allyl peroxy radicals", J. Chem. Soc. Faraday Trans. 89, 433-446 (1993); DOI: 10.1039/FT9938900433
COMMENTS: The laser flash photolysis technique, coupled with UV absorption spectroscopy, has been used to measure the absorption sprectrum

The allyl radical was generated by the 193 nm photolysis of hexa-1,5-diene/N2 mixtures, or the 248 nm photolysis of allyl iodide/N2 mixtures

Data from Table 3

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